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DOI:10.1002/ADFM.200800622 - Corpus ID: 41580582
@article{CroweWilloughby2009FormationAP, title={Formation and Properties of Responsive Siloxane‐Based Polymeric Surfaces with Tunable Surface Reconstruction Kinetics}, author={Julie A. Crowe-Willoughby and Jan Genzer}, journal={Advanced Functional Materials}, year={2009}, volume={19}, url={https://api.semanticscholar.org/CorpusID:41580582}}- Julie A. Crowe-Willoughby, J. Genzer
- Published 10 February 2009
- Materials Science
- Advanced Functional Materials
Here, the formation of responsive polymeric materials with tunable response time is reported. These structures are fabricated by chemically modifying poly(vinylmethyl siloxane) (PVMS) networks with alkanethiols bearing a hydrophilic end‐group (COOH or OH). The response time is facilitated by the liquid nature of the PVMS backbone and increases with increase in length of the methylene spacer (CH2)n in the alkanethiol pendent group. While for n = 2 and 6, the surface reconstructs almost…
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24 Citations
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umerous experimental probes, including optical microscopy, Fourier-transform infrared spectroscopy, surface contact angle, ellipsometry, and nanoindentation are utilized to interrogate the physical and chemical characteristics of these PVMS-TCS coatings.
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- M. MishraChristian Schöttle Alexander Katz
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We demonstrate synthesis of polysiloxane-modified inorganic-oxide nanoparticles comprising a TiO2-based pigment (Ti-Pure R-706), which undergo drastic wettability reversal from a hydrophilic wet…
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It was found that the phosphatidylcholine groups could enrich on the surfaces and subsurfaces with the help of the fluorocarbon chains and self-assemble into mimic biomembrane on these polymer surfaces.
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